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Tris(2-Aminoethyl)amine cas 4097-89-6

  • Tris(2-Aminoethyl)amine cas 4097-89-6...
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Detailed introduction



English synonyms

Tris(Aminoethyl)amine;tris(Beta-Aminoethyl)amine;2,2',2''-Triaminotriethylamine,97%tren;2,2'',2-Triaminotriethylaminetren;2,2μ,2μμ-Nitrilotriethylamine,2,2μ ,2μμ-Triaminotriethylamine,Taea;2,2',2''-Nitrilotris(Ethane-1-Amine);2,2',2''-Nitrilotrisethanamine;tris(2-Aminoethyl)amine,95%

Physical and chemical properties

Aliphatic nitrogen tetramines such as tris(2-aminoethyl)amine can be used in research and industrial fields such as chelating agents, corrosion inhibitors, resin curing agents, catalysts, and organic intermediates. Its outstanding structural feature is that there are 4 N atoms with strong coordination ability in the molecule, which can form stable chelates with a bicyclic structure with most metal ions.

resolve resolution

In a 2000 ml glass reactor, 120.5 g of nickel hydroxide and 146.2 g of tris(2-aminoethyl)amine were added to 2000 ml of H2O. The solution was stirred at 50°C for 8.5 hours. Excess nickel hydroxide was removed by centrifugation (30 min, 4400 rpm). The solution was recovered by decantation to obtain the title compound tris(2-aminoethyl)amine. The exact concentration of nickel was determined using inductively coupled plasma coupled optical emission spectroscopy (ICP-OES). The synthesis route is shown in the figure.

Melting Point-16 °C
Boiling Point114 °C/15 mmHg (lit.)
Density0.976 g/mL at 20 °C (lit.)
Vapor density5 (vs air)
Refractive Indexn20/D 1.497(lit.)
Flash point>230 °F
Storage conditions2-8°C
SolubilitySoluble in chloroform (a small amount), DMSO (a small amount)
FormSaline Suspension
Acidity coefficient (pKa)10.00±0.10(Predicted)
ColorTransparent yellow
Proportion0.977
Water SolubilityMiscible with water.
SensitivityHygroscopic
BRN1739626
StabilityStable. Hygroscopic. Absorb Carbon Dioxide from the Air. Incompatible with Strong Acids and Strong Oxidants.

Use

Can Be Used as a Structural Unit of Cryptand; 1 Precursor of Organic Nonionic Superbase (A Nonionic Strong Base).

Use

It Can Be Used as the Structural Unit of Cryptand and the Precursor of Organic Nonionic Superbase.


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