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      Barium titanate CAS 12047-27-7

      • Barium titanate CAS 12047-27-7...
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      Detailed introduction



      CAS number:12047-27-7
      molecular formula:BaO3Ti
      molecular weight:233.19
      EINECS number:234-975-0

      English synonyms

      bariummetatitanate;bariumtitaniumtrioxide;titanatebarium(1:1);vk4;vk4(oxide);yv100an;titanate barium;Bariumtitanatesinteredlumpmmwhitepieces

      Related categories

      Cv Inorganic Chemical Products for Electronics Industry;Barium;Catalysis and Inorganic Chemistry;Agricultural and Veterinary Raw Materials;Ca Barium Compounds;Inorganic Chemical Products;Inorganic Salts;Coating Materials;TitanatesChemical Synthesis;Catalysis and Inorganic Chemistry;Ceramics;BariumMetal and Ceramic Science;Chemical Synthesis; Inorganic Chemical Raw Materials; Other Functional Powders - Barium Titanate; Raw Materials; Functional Additives Chemical Raw Materials; Metal Compounds - Titanium Salts; Functional Materials; Oxides; Raw Materials; Chemical Raw Materials; Fine Chemical Raw Materials; Chemical Materials; Industrial/Fine Chemicals;Inorganics;Metal and Ceramic Science;Titanium;56: Ba;Materials Science;Nanomaterials;Nanoparticles: Oxides, Nitrides, and Other CeramicsMetal and Ceramic Science;Nanopowders and Nanoparticle Dispersions;TitaniumNanomaterials;metal titanate

      Introduction

      Barium titanate (BaTiO3) is a typical perovskite crystal with high dielectric constant, low dielectric loss, large resistivity, high compressive strength and excellent insulating properties. It is widely used in many Layer ceramic capacitors (MLCC), thermistors (PTCR), electro-optical devices and dynamic random access memory (FRAM) are the basic raw materials for electronic functional ceramic devices, so they are called the backbone of the electronic ceramic industry by scholars and manufacturers. .
      Barium titanate is a uniform molten compound with a melting point of 1618°C. It has five crystal forms: hexagonal, cubic, tetragonal, tetragonal, and trigonal; it is stable in tetragonal form at room temperature.

      Melting point

      1625 °C

      Density

      6.08 g/mL at 25 °C(lit.)

      Vapor Pressure

      0Pa at 20℃

      Storage conditions

      no restrictions.

      Solubility

      Soluble in alcohols

      Shape

      powder

      Color

      White to gray

      Specific gravity

      6.08

      PH value

      9.6 (20g/l, H2O, 25℃)(slurry)

      Water solubility 

      INSOLUBLE

      Merck 

      14,1000

      InChIKey

      WNKMTAQXMLAYHX-UHFFFAOYSA-N

      LogP

      1 at 20℃

      CAS database

      12047-27-7(CAS DataBase Reference)

      White powder. Soluble in concentrated sulfuric acid, hydrochloric acid and hydrofluoric acid, insoluble in hot dilute nitric acid, water and alkali.

      ●  Mainly used for the preparation of various electronic components such as electronic ceramics, PTC thermistors, capacitors, etc.

      ●  Widely used in the electronics industry, it can be used to manufacture nonlinear components, dielectric amplifiers, memory components of electronic computers, and also used to manufacture microcapacitors with small volume and large capacitance. It can also be used as a material for the manufacture of components such as ultrasonic generators.

      ●  It is mainly used in the electronics industry as a material for the manufacture of nonlinear components, dielectric amplifiers, memory components of electronic computers, microcapacitors and ultrasonic generators.

      ●  After mixing the purified titanium tetrachloride solution and the purified barium chloride solution, at 70 ~ 100 ℃, add purified oxalic acid (the ratio of TiCl4: BaCl2: H2C2O4? 2H2O is 1:1:2) to react to generate titanium oxalate The barium is precipitated, filtered, washed, dried, calcined at 700-1000°C, and then sieved to obtain high-purity barium titanate. That
      TiCl4+BaC12+2H2C2O4+5H2O→BaTiO(C2O4)2?4H2O↓+6HCl
      BaTiO(C2O4)2?4H2O[△]→BaTiO3+4H2O+2CO2↑+2CO↑

      ●  Oxalic acid precipitation method After mixing the purified titanium tetrachloride solution and the purified barium chloride solution, at 70 ~ 100 ℃, add purified oxalic acid (the ratio of TiCl4:BaC12:H2C2O4·2H2O is 1:1:2) to react to generate The barium titanyl oxalate is precipitated, filtered, washed, dried, calcined at 700-1000°C, and then sieved to obtain the finished barium titanate. That
      BaCl2+TiCl4+2H2C2O4+5H2O→BaTIO(C2O4)2·4H2O↓+6HCl
      BaTiO(C2O4)2·4H2O→BaTiO3+4H2O+2CO2↑+2CO↑
      The barium carbonate and titanium dioxide are mixed (1:1) and ground by solid-phase method, then extruded and calcined at 1200°C. finished product.
      BaCO3+TiO2→BaTiO3+CO2↑

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